On Route 38 and 39
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You catch Snubbull in Route 37 and 38
Snubbull is a rare Pokemon that can only be found in the Safari Zone extension in Pokemon Emerald.
You'll need to trade from Pokemon Emerald.
In Pokémon HeartGold you can find wild Snubbull at Level 13 in Route 38 additionally you can find it as a Swarming Pokémon in Route 38 but the swarming Snubbull can be found at the minimum level of Level 13 and the maximum level Snubbull of Level 16.
trade granbull (its evouloution) from colloseum, then breed