To find Pikachu, enter the Safari Zone and go directly to the left. Like just keep going left until there's no more road. Then look around the patch around that area until a Pikachu shows up. Seeing how it's rare it'll take a while
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You can find a pikachu while in the safari zone. Pikachu also cannot be found anywhere else.
In Verdanturf, in a house. A lady with a Pikachu.
thunder stone
In pokemon fire red, leaf green, red, blue, soulsilver, heartgold, silver, and gold pikachu can be found in Viridian forest. In pokemon Sapphire, ruby, and emerald you can find it in the safari zone
Put 2 pikachu in the day care