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Janine, the new Gym Leader of the Fuchsia City Gym will give you TM06 Toxic as a reward for beating her in a match.
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Janine gives you it when you defeat her.
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How do you get TM 06 in Pokemon emerald?
Tm 06 is toxic. You can find it in fiery path. You need strength to get to it however, and possibly rock smash, i am not sure about that. Anyways, go up or down the fiery path (try to bring a repel or two along) until you see a boulder. Then move the boulder, and the remaining boulders as well to the side. t is like a puzzle. Do not trap yourself away from it, but if you do, just get out of fiery path and try again. You can also find a fire stone this way.
