Right-most side of the Safari Zone on Route 121. They're quite rare (and tricky) to catch.
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You can find a pikachu while in the safari zone. Pikachu also cannot be found anywhere else.
In Verdanturf, in a house. A lady with a Pikachu.
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In pokemon fire red, leaf green, red, blue, soulsilver, heartgold, silver, and gold pikachu can be found in Viridian forest. In pokemon Sapphire, ruby, and emerald you can find it in the safari zone
Put 2 pikachu in the day care