you'll find it in the cave on top of the last city in Jhoto with the icey floor, you will find it after the big ice floor that takes a long time to pass you'll find it in a small ice place you'll see the red ball in there, that's waterfall good Luke buddy
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you can find it in waterfall cave in kanto
almost all of the water type Pokemon can learn and use waterfall
The HM waterfall is in the ice cave, the cave you use to get to Blackthorn City to get the 8th badge. Just pick up every item that you can see in there and you will find it.
In the Ice Cave between Mahogony and Blackthorn.
You can find Waterfall in the Dark Cave.