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You get the flute in the Pokemon tower after you get the silph scope.
Piplup does not exist in Pokemon LeafGreen or FireRed.
You can find the Poke Flute in the Pokemon Tower. After you free Mr. Fuji, he will give you the Poke Flute.
Rescue the guy who's at the top of Pokemon Tower in Lavender Town and as a gift, he'll give you the marvelous PokeFlute!!
You cannot catch houndour in Pokemon leafgreen either get one from Pokemon emerald or Pokemon colosseum.