Battle Frontier prize and inside S.S. Tidal bin; rare Pickup item when at least level 81
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Leftovers are an item that you can give to Pokemon to hold. In Pokemon Emerald, you can get them from the bins on the SS Tidal.
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The Game Corner is located in Mauville City.
It is Altering Cave which you can enter only after you beat the Pokemon league.
its not an emerald its RAYQUAZA the main legendary Pokemon in Pokemon emerald.