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you go to lake valor, where you'll meet the Pokemon master Cynthia. she'll give you the secretpotion, which you spray on the psyducks to get past them.
near solaceon town and besides the momoo shop thing!
You get the potion from Cynthia at Valor Lakefront. Then go to route 210 where the psyducks are.
The Psyducks are right above Solaceon City.
After you have defeated leader wake in pastoria city, Cynthia will give you a secretpotion, go to the psyducks and they will go away