Snivy evolves at level 16
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Snivy evolves into Servine at level 17 and Servine evolves into Serperior at level 36.
There are only a few ways to get a Snivy in Pokemon Black:1.) Obviously, you can choose Snivy as your starter Pokemon in the beginning2.) You can go to the Global Trade Link (which can be accessed in any Pokemon Center on the 2nd floor) and trade one of your Pokemon for Snivy OR you can trade a pokemon for either a Servine or a Serperior and breed it to get a baby Snivy.
Snivy evolves at level 17, however you must complete the game first if the Snivy is you or your partner.
Ash's Snivy didn't evolve yet.
The starter Pokemon are Snivy, Tepig, and Oshawott.