Gengar learns the move Destiny Bond at level 39 in Pokémon FireRed and LeafGreen. Gengar can potentially know Destiny Bond at level 33 by leveling Gastly to level 33 before evolving it which will let it learn Destiny Bond.
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Yes, you can learn a Mismagius Destiny Bond by breeding a female Mismagius with a male Gastly, Haunter, Gengar Koffing, Weezing, Wobbuffet, Ralts, Kirlia, Gardevoir, Gallade, Gulpin, Swalot, Shuppet, Banette, Duskull, Dusclops, Dusknoir, Drifloon, Drifblim, Spiritomb or Rotom.
Put it in a daycare with wynaut
you can't theres no such thing but cacnea and wynut can learn it
gengar can't learn scary face unless breeded
no