The best way to train herb lore at level 35 would be to get a clean toad flax and some toad legs and a vial to make agility potions until you can make a higher potion.
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The best place to train typhlosion is Route 26 in The Kanto regoin.
sleuthound Tercessuinotlim
The best place to train a lvl 20-30 Lucario is up by Snowpoint city. Fighting types like him are really good there.
It's pretty obvious... EV train (I suggest EV Training in Defense)...
you should train sycher against fire and pshcik pokemon:D