misty
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Ash never kissed any gym leader, and that includes Misty.
She is the 2nd gym leader ;))
When he went to fight the Cerulean City gym leader, her 3 sisters were going to give him the badge without fighting, so she stepped up to uphold the honor of the gym.
If you were a Pokemon series' character you could patch up with Ash and his friends to get to the Cinnabar Island team leader.
claire