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Uxie is indeed a rare Pokemon appearing only once in the games it can be caught in. Uxie is part of a classification of Pokemon called Legendary Pokemon. Legendary Pokemon are the rarest Pokemon and can only be caught once per game they appear in.
Uxie
memmemem whatever that means,#146 is Uxie
You can't capture Uxie more than once on this game, but you can own more than one Uxie if it is traded to you.
before you do anything SAVE! this is so if you don't manage to catch uxie you can still do it again. firstly get its hp down using a Pokemon with good stats. then get a Pokemon with about the same level as uxie (level 50) and use a low lower attack till the uxie's hp is really low. then use whatever type of poke balls you like (i recommend ultra balls and dusk balls) till u have caught it. hope this helped!