They can learn splash (lvl 1)....tackle (lvl 15) and flail (lvl 30)
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The best Pokemon to have in Pokemon diamond is Arceus because he has the best stats in Pokemon diamond. Answer 2 Marowak and Latios are better. Answer 3 Dragonite would have to be the best! It has great stats, is immune to a lot of types and can learn many moves like fire-type moves to deal with super effective ice-types.
If the boulders are smooth then you need to get one of your Pokemon to learn strength to move it and if the boulder is rough then you need to get your Pokemon to learn rock smash ( both of these moves require HMs to be learnt)
i would say chimchar because he can learn moves like blast burn and close combat.