You can check what moves Quilava can learn here: http://bulbapedia.bulbagarden.net/wiki/Quilava_%28Pok%C3%A9mon%29#Learnset
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Quilava will evolve in to typlotion at 36 before it gets the attack Flame-wheel at 41.Mr.Seidschalg
Actually if you want you can pick cyndaquil in the beggining of the game and quilava can learn cut
it can learn Grass and Psychic moves
60 if you dont evolve quilava he learns it at level 54 then evolve it
This moveset is based on in Pokemon FireRed/LeafGreen/Ruby/Sapphire/Emerald Quilava can learn these moves by leveling up: Tackle, Leer, Smokescreen, Ember, Quick Attack (level 21), Flame Wheel (level 31), Swift (level 42), and Flamethrower. (level 54) By TM and HM: Focus Punch, Roar, Toxic, Hidden Power, Sunny Day, Protect, Frustration, Return, Dig, Brick Break, Double Team, Flamethrower, Fire Blast, Aerial Ace, Facade, Secret Power, Rest, Attract, Overheat, Cut, Strength, and Rock Smash.