If you want a physical moveset, level 43 would be when is learns Crunch, but if you want a special moveset, level 22 would be fine because in my opinion, Brine is a terrible move.
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it does not evolve by level up, you have to give panpour a water stone for it to evolve into simipour
You can evolve it with a waterstone.
at level 43 because at that level its gonna learn the last move that it can learn and when u evolve it there are no moves that it can learn
To evolve Pansage/Panpour/Pansear you have to use a leaf stone on Pansage, a water stone on Panpour, and a fire stone on Pansear.
Panpour evolves through a Water Stone. However, if you evolve it, the newly-evolved Simipour will not learn any more moves through leveling up. Water Stone can be obtained from a scientist in Castelia City located at the first pier.