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You can't catch wild Poliwhirl. You catch Poliwag though. Evolve your cute Poliwag into Poliwhirl by using a water stone. You can probably buy water stones in the department store in Celadon City.

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Q: What level is a poliwhirl in the wild Pokemon Yellow?
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Related questions

How do you get a kings rock in Pokemon platinum?

celestic town, wild poliwhirl


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How do you get the king stone for Pokemon pearl?

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Which Pokemon evolve with kings rock?

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When does Ivysaur evolve in yellow?

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