it evolves by happiness at daytime!
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Riolu evolves when Level Up by Happiness Value at 220 During the Day
Riolu doesn't evolve at a specific level. It evolves with maximum friendship.
answer riolu doesnt evolve by level it evolves by care and love
Riolu evolves into Lucario at level 14. (But if evolution is skipped, it will try to evolve at every level up after that as well.)
Riolu evolves with Happiness but only during the day.