It evolves via Fire Stone, not leveling.
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Vulpix evolves into Ninetales via a Fire Stone.
Catch a Vulpix on Route 7, 8, 36, 37 or 48, then evolve it using a Fire Stone.
Vulpix cannot evolve by leveling up. You will need a firestone so that it can evolve to become Ninetales.
In Pokemon LeafGreen, to get a Ninetails, you must first capture a Vulpix. Vulpix can be found on Routes 7 and 8, and in the Pokemon Mansion. Once you have obtained a Vulpix, a Fire Stone is needed to evolve it into a Ninetails.
None - you use a fire stone to evolve it into Ninetales