Same as on every game. Level 31
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Venonat evolves into Venomoth, starting at level 31.
You don't need to use an evolution stone to evolve Venonat. It evolves to Venomoth at level 31.
Level 31
Ariados does not naturally learn the move Signal Beam in Pokemon Emerald. If bred with Venonat, Venomoth, or Volbeat however it will learn Signal Beam.
Wooper will evolve at Level 20.