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Lilipup evolves into Herdier at level 16.
Stoutland is the last Evolution of its chain. You were probably thinking of Herdier. Lilipup level 16 evolves to Herdier and Herdier level 32 evolves to Stoutland.
Lillipup cannot learn ember.
It is suppose to evolve at the Level of 20,but if you want it to evolve later it can evolve anything after it is at Level 20.
It will evolve by level. Teddiursa will evolve into a Ursaring at level 30.