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Assuming you are playing Pearl, Diamond, Platinum, HeartGold or SoulSilver, it won't learn it via leveling up, you must use the valuable TM26; but it is a good choice of Pokemon to use it on.

You can get the TM from Wayward Cave, and some other places, which I can't be bothered to list right now, I'm currently underground trying to find Heart Scales in Pokemon Pearl.

HEART SCALES FTW!!!!

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13y ago

What else can I help you with?