Entei can learn TM22- Solarbeam.
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level 65
Lvl. 60
Venusaur learns Sloarbeam at level 53.
sceptile cannot learn solarbeam. it can only learn it through TM22 WRONG! Sceptile CAN learn Solarbeam WITHOUT the TM. Trust me. It works on Diamon, Pearl, Platinum, HeartGold, and SoulSilver. All versions I own copies of. Generally Sceptile will lear Solarbeam, in those games at least, around lvl 75. it say EMERALD NOT Diamon, Pearl, Platinum, HeartGold, and SoulSilver
You can't teach a Roselia Solarbeam without using a TM and only finally evolved starter grass Pokemon can learn Frenzy Plant.