charzard learns slash at lvl.44
hope this helps(:
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the black charizard is actually a *shiny* charizard. so, if you just happen to get a shiny charmander/charmeleon, when you evolve it, it will become a black charizard.
Defog did not become a move until Generation 6 so you will not be able to find it in LeafGreen
A Charcolt is a special Pokegod that is the final evolution of Charizard. Once you give your Charizard a special stone (not so sure what the stone is called. Sorry!), it will become a Charcolt. Another Charizard based Pokegod is Skelozard. To see Pokemon Red and Blue Gameshark codes for some Pokegods, visit www.pokemon-guide0.tripod.com/id3.html. =D
Charizard, but they all become powerful in different ways so it is almost impossible to tell. Blaziken uses all out fire. Charizard becomes powerful in stamina and guts. Typhlosion becomes powerful in speed and guts. Infernape learns to use all of the above categories but isn't as powerful in any of them. Charizard excels in Attack Blaziken excels in Defense Typhlosion excels in Speed Infernape excels in Special Attack End of Story.
You can't help her, she's just there as an example of disobedient Pokemon. (Pokemon become disobedient if you've leveled them too high before getting the badge that allows Pokemon to obey that certain level (i.e. cascade badge grants obedience from any Pokemon up to level 30))