it evolves only with the leaf stone
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Exeggcute doesn't evolve by levelling up. It evolves into Exeggcutor when exposed to a Leaf Stone.
Exeggcute evolves when you use a leaf stone on it.
You should evolve exeggcute at about level 25-30, so some good moves can still be learned by Exeggutor.
leaf stone
Exeggcute evolves with leaf stone. For more info click link below.