It evolve at 16 in Prinplup and then on 36 in Empoleon
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Piplup will attempt to evolve once it reaches Level 16.
piplup will evolve at lvl 16 (prinplup) and lvl 36 (empoleon)
Piplup evolves into Prinplup at level 16 and Prinplup into Empoleon at level 36
prinplup at Level 16
Piplup evolves at lv.16 and prinplup evolves into empoleon at level 36