Skarmory learns Steel Wing at level 38
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It can learn Steel Wing by TM. It can also learn Steel Wing by level up, learning it at level 32.
It learns it at level 34
Skarmory can learn Leer, Peck, Sand-attack (Level 10), Swift (Level 13), Agility (Level 16), Fury Attack (Level 26), Air Cutter (Level 29), Steel Wing (Level 32), Spikes (Level 42), and Metal Sound. (Level 45). By TM/HM it can learn Roar, Toxic, Hidden Power, Sunny Day, Taunt, Protect, Frustration, Return, Double Team, Sandstorm, Aerial Ace, Torment, Facade, Secret Power, Rest, Attract, Thief, Steel Wing, Cut, Fly, and Rock Smash. Note: This is only in Pokemon Ruby, Sapphire, Emerald, FireRed, and LeafGreen.
Level 33
Pidgeotto learns wing attack at level 27