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Blaziken can't learn close combat. But if you have a Blaziken and want it to learn a powerful fighting type move I suggest you try the TM 52: Focus Blast. It works a lot better since most rock and steel types have a lot higher defense than sp.def, and it doesn't make you defense go down like close combat.
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Earn +20 ptsQ: What level does Blaziken learn close combat?
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