Blaziken can't learn close combat. But if you have a Blaziken and want it to learn a powerful fighting type move I suggest you try the TM 52: Focus Blast. It works a lot better since most rock and steel types have a lot higher defense than sp.def, and it doesn't make you defense go down like close combat.
heracross learns close combat at a level of 37.
Gallade learns close combat at level 53
Blaziken does NOT learn flamethrower. but torchiccan. at level 42 i think!
Level 65
level 37
Infernape will learn Close Combat at Level 41.
heracross learns close combat at a level of 37.
Gallade learns close combat at level 53
Hariyama learns Close Combat at level 52.
Cobalion learns Close Combat at level 73.
Blaziken does NOT learn flamethrower. but torchiccan. at level 42 i think!
Level 65
level 37
levil 53
Blaziken learns Sky Uppercut in level 67.
Riolu doesn't learn Close Combat, however Lucario learns Close Combat at Lv 42 (DPPt, HGSS) and Lv 55 (BW,BW2).
Because Staraptor does not learn Close Combat until Level 34, and Staravia cannot learn Close Combat at all without cheating. To make Staraptor learn/re - learn Close Combat, take it and a Heart Scale to the Move Tutor in Pastoria City