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Since neither Pikachu, nor Raichu learn any speed boosting moves, so far as I know (Agility, Rock Polish, etc), the best way, is to get a Pikachu with a nature that raises Speed, EV train it for speed, and hopefully have decent IV's. Then evolve it. If you rely on TM's for it's Movesets, you can evolve a bred Pikachu at Level 1, thereby getting slightly higher stats, than if you evolved it later.

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Q: What is the way to boost speed for Raichu in pokemon platinum?
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