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The Choice Band can be bought from a vendor on Pokemon Platinum in the Battle Frontier for 48 BP. To get BP simply take part in the various special battle arenas within the Frontier.
take the ferry from lilycove or slateport and Scott will be on the ferry and tell you thenext ferry you take is going to the battle frontier.
Battle points may be obtained by beating games in the Battle Frontier, such as the battle tower where you take on 7 trainers with three pokemon. You could also do the battle castle.
It's not available to catch but it does exist. Go to the Battle Frontier. Take the Battle Pyramid challenge. It is one of the Pokemon you encounter.
You battle Barry's father after you have completed 21 battles successfully in the Battle Tower. This may take several attempts to complete.