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The only way you can get a Lucky Egg in Pokemon FireRed or LeafGreen is to go to the Safari Zone and catch a Chansey. It's very rare to get one because it's only a 5% chance a Chansey will be holding one. Chanseys are very hard to find, catch, and they always run away. Also if you have Pokemon XD you can get a Lucky Egg by doing a quest and then trading it to Pokemon Ruby, Sapphire, Emerald, FireRed, and LeafGreen versions.
The item Lucky Egg, that doubles the Exp.Points earned in battle, can be obtained by catching a Chansey in the Safari Zone. You will have to be lucky though, since there is not really that high percentage of getting a lucky egg with the Chansey you catch (and it is not easy to meet a chansey, nor catch it, either...). As a sidenote, I actually got lucky as hell and receive a lucky egg on the third Chansey I ever caught in Firered. If I forgot to mention it, the Chansey will be HOLDING the item, in case you are lucky enought to catch a chansey with it.
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Players can only get the lucky egg in Pokemon Pearl from the wild Chanseys. Lucky eggs are very difficult to find in the game.
The lucky egg is an item that doubles the amount of exp that a Pokemon gives. You can get it from a Chansey if you are lucky (found near Solaceon town).