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Beat everything in career mode up to and including the eighth tier to unlock the guitar battle with Lou (TDWDTG). To get the song as a single player song you will have to download (for free) the Boss Battles song pack via Xbox Live on the Xbox 360 version of the game.
You can only play it in Career versing Lou on PS2 and Wii. You can download the song on PS3 and Xbox 360 to play as a song.very difficult to beat the devil on that level but practise hard!
The thick izzy style for Lou is only unlock for ps3 and xbox 360 plus you can get thick izzy by downloading it from xbox live or wii fit
The characters in guitar hero are Starter Characters: Axel Steel Casey Lynch Izzy Sparks Judy Nails Jonny Napalm Lars Umlaut Midori Xavier Stone -=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-=-= Un-Lockable Characters: Grim Ripper God of Rock Tom Morello from RAGE AGAINST THE MACHINE! Slash from Guns N Roses Lou the Devil Elroy Budvis Metalhead
finish every song in career mode