The word pizzazz ends with a z. It means the quality of being exciting or attractive.
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A five (5) letter word that starts with Z and ends with F, there is none recorded. However, there is a word that starts with Z and ends with F. The word is a four (4) letter word: zarf, (noun) a metal holder for a coffee cup.
jazz
wiz?
blitz
Zulu. It's the word that stands for 'z' in the policeman's alphabet.