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no its not sympothy for the devil its the devil went down to Georgia by charlie Daniels band
no you cant
You can only play it in Career versing Lou on PS2 and Wii. You can download the song on PS3 and Xbox 360 to play as a song.very difficult to beat the devil on that level but practise hard!
the thing is, you cant. The Devil Went Down To Georgia is part of the Boss Battles track pack. which you'll have to download, the plus side is, you get to play Guitar Battle VS Tom Morrello(Wicky Wicky Warzone as i call it) and Guitar Battle VS Slash(Snakepit Showdown, also my name for it.) So. unless your willing to shed out some cash for some Microsoft points, you're not getting the song.