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You have basically completed the game. You can also get the 151st Pokemon (Mew) but you can only do it through an in game glitch (search it on YouTube) or by using a cheat device. You can also go to Celadon City and go to the Large Building and talk to the Game Designers the game creater will give you a diploma whether you have caught 150 or 151 Pokemon.

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Q: What happens when you have caught all 150 Pokemon on Pokemon Blue?
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