ash's pigeotto evolves in the first episode of season 3 (or 2 im not sure) but then he lets it go right after it evolves to protect the pigey from the spearow and fearow
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Episode 83 - Pallet Party Picnic
the episode that ashs grovyle evolves is odd Pokemon out that's the name of the episode and the season is battle frontier
pidgeotto will evolve at level 36
Train Pidgeotto to Lv 36.
Pidgeotto evolves starting at Level 36. At Level 18 , Pidgey evolves into a Pidgeotto and at level 36 Pidgeotto evolves into a Pidgeot.