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Ash's Pikachu, Squirtle and Bulbasaur have never evolved and they never will.

-Pikachu is a main character and therefore his appearance changing would be a ton of extra work, also it would not look right for the main character to change.

-Bulbasaur and Squirtle are no longer with Ash and Bulbasaur currently resides at Professor Oak's lab while Squirtle stays with the Officer Jenny in charge of the Squirtle Squad.

To evolve a Pikachu in-game, use a Thuderstone on it.

To evolve a Bulbasaur, level it up to level 16.

To evolve a Squirtle, level it up to level 16.

As seen in "Bulbasaur's Mysterious Garden" Bulbasaur tried hard not to evolve.

In the episode "Electric Shock Showdown" Pikachu had a chance to evolve into Raichu, but did not want to.

Ash's Squirtle has shown no opinion towards evolving further but because of its ties to the Squirtle Squad and its friends there, it's unlikely it will evolve.

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Q: What episode does Bulbasaur Squirtle and Pikachu evolve?
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