It doesn't evolve, but it changes forms with the help of a Gracidea Flower.
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shaymin can not evolve
Shaymin cannot evolve.
The land Shaymin. Your choice is to make it land or Sky. But it doesn't technically evolve. It transforms into a Sky Shaymin.
Well, first of all, I have to mention the error that I just corrected in the question. SHAYMIN is a Legendary Pokemon. CHARMIN is a brand of toilet paper. Now that that's been cleared up, let me first explain that Shaymin does not evolve. It changes form like Deoxys and Arceus. You must have an EVENT Shaymin, and travel to Floaroma Town. Somewhere in Floaroma, with the Event Shaymin in your party, you will receive a Gracidea Flower after talking to someone. Exposing this to Shaymin will change its form to Sky Forme and back to Land Forme. Shaymin cannot be in Sky Forme if it is frozen.
You CANT but you could get the gracidia flower.Talk to the lady in flamora town if you have shaymin in your party she gives you the flower then use it on shaymin and it will turn to sky forme.ps dont trade the shaymin from a diamond or pearl game and try to get the flower i tryed and it didnt work.