"What do you use premier balls for on Pokemon leaf green?"
On Pokemon leafgreen you use premier balls to catch Pokemon.
They are a fancier version of the pokeball.
How to obtain: Buy 10 pokeballs and receive 1 premier ball as a gift.
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Use master balls. Use a ton of ultra balls and put them to sleep or paralyze but master balls are your best bet since leaf green is harder than its original counterpart
Use a moon stone on it.
You have to use Pokeballs, Great Balls, Ultra Ballsect.Many Pokemon can't be caught in Leaf Green, like Mew unless you go to an event, but all events for Leaf Green and Fire Red have ended.
i think a Oddish or Vileplume could use it
Rock smash