These are some good moves for your hitmonlee they are: Earthquake, Rock tomb, Brick Break, and Mega Kick it learns Mega Kick at LV.46 in Fire Red version.
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Trade it for a better Pokemon like they say "you can't teach a old dog new tricks" and how i say to that qoute if you can't get a better one.
There are move tutors everywhere there is one in particular that will teach moves that your Pokemon tried to learn but didn't that tutor can be found on two island.
If you still have the TM/HM, teach it to the Pokemon again. If not, go to the move deleter-- there should be a move tutor there too. I learned through HG/SS though. |D
You get the HM rock smash and teach it to one of your Pokemon. You get it on island 1.
I assume you mean the one above the waterfall/ river? If so, you must move your Charizard into slot 1 of your Pokemon team. Make sure he's fully evolved and is the first pokemon in the team.