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  1. St. Kitts and Nevis
  2. St. Lucia
  3. St. Vincent and the Grenadines
  4. Samoa
  5. San Marino
  6. Sao Tome and Principe
  7. Saudi Arabia
  8. Scotland (part of the United Kingdom)
  9. Senegal
  10. Serbia
  11. Seychelles
  12. Siam (now Thailand)
  13. Sierra Leone
  14. Singapore
  15. Slovakia
  16. Slovenia
  17. Solomon Islands
  18. Somalia
  19. South Africa
  20. South Korea
  21. South Sudan (On July 9, 2011, southern Sudan became the independent country of South Sudan.)
  22. Spain
  23. Sri Lanka
  24. Sudan
  25. Suriname
  26. Swaziland
  27. Sweden
  28. Switzerland
  29. Syria
  30. * Sahrawi Arab Democratic Republic (disputed, partly-recognized Western Sahara claimed by Morocco)
  31. * Somaliland (disputed, unrecognized region of Somalia)
  32. * South Ossetia (disputed, Russian-allied region of Georgia)

Other territories and subdivisions that start with S:

  • Saint Helena (UK overseas territory)
  • Saint Martin (French overseas collectivity)
  • Saint Pierre and Miquelon (French overseas collectivity)
  • Saint-Barthélemy (French overseas collectivity)
  • Scotland (UK)
  • Siberia (Russia)
  • South Georgia and the South Sandwich Islands (UK)
  • Svalbard (northernmost Norwegian islands)

Switzerland, Slovenia
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