Oh, dude, you're hitting me with the tough ones! Okay, so technically speaking, there are words like "embellished" and "entrenched" that fit your criteria. But like, who really thinks about this stuff, right? Just go with "banana" or "avocado" and call it a day.
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Abracadabra, agoraphobia, albuminuria, amphisbaena, antonomasia and astrocytoma are 11 letter words. They begin and end with the letter a.
Alliteration
11 letter words that begin and end with the same letter:charismaticdisappeareddiscrediteddistributedgalvanizinggerminatingseriousnesstranslucenttransparent
Some words that begin and end with the same letter and contain CA are:abracadabraacaciaacademiaalpacabicarbcarcinogenicdecaffeinateddecanteddecapoddecayeddedicateddefecateddesiccateddiscarddislocatedduplicatededucateencapsulateencaseequivocateeradicateescalateescapadeescapeescaroleevocativeexcavateexcommunicateexplicateextricatelackadaisicalliturgicallocallogicallogisticallyricalmacadamminicamnotificationnullificationscabiesscalesscallopstelecasttomcattoxicanttypecast
Algebra, alfalfa, ammonia, amnesia and antenna are 7 letter words. They begin and end with the letter a.
Hundreds of eight letter words begin and end with the same letter. A few of those words include academia, backstab, cosmetic, drunkard, elegance, grunting, hyacinth, knapsack, landfill, mushroom, nitrogen, ocotillo, pawnshop, reporter, sickness, twilight and withdraw.