The characters present in Super Smash Bros Brawl are:
Mario
Link
Yoshi
Fox
Kirby
Pikachu
Samus & Zero Suit Samus
Ness
Captain Falcon
Jigglypuff
Luigi
Pokemon Trainer*
Squirtle, Ivysaur, Charizard*
Wario
King Dedede
Pit
Captain Olimar
R.O.B
Mr Game & Watch
Lucas
Solid Snake
Sonic
Marth
Ike
Zelda & Sheik
Metaknight
Falco
Wolf
Peach
Bowser
Ice Climbers
Toon Link
Diddy Kong
Lucario
*Pokemon Trainer and his pokemon are considered seperate characters. You do not actually play Pokemon Trainer however he just commands the three pokemon listed above.
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35 characters are in super smash bros brawl
You can not use Miis as characters in Super Smash Bros Brawl.
There are 35 playable characters in Super Smash Bros Brawl.
Super Smash Bros., Super Smash Bros. Melee, Super Smash Bros. Brawl, Super Smash Bros. for Nintendo 3DS/ Super Smash Bros. for Wii U, Super Smash Bros. Ultimate.
You can only install Super Smash Bros. Brawl on your Wii with a Super Smash Bros. Brawl disc.