Monkey, badger, rabbit are a few examples of animal words that have two syllables. There are quite a few more.
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Some words with two syllables that start with D are:dentistdonkeydaggerdevildimpledragondaughterdaddydampendrippingdoughnutdungeondeadbeatdreadfuldamagedoubtfuldangledecentdapperdeltadoweldappledriverdelugedaisy
The word "sixty."
coffeetoffeesettee
Spoonerism is the unintentional exchange of letters or syllables between two words or even within a word. The word derives from a 19th Century Clergyman. Also Metathesis is the reversal of letters within a word.
sixty