gengar
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.You need a hauter.use scary face and then X accuracy. Then use hipnosis and throw ultra ball.
battle the Pokemon you think has the move block or scary face and then capture it
Pokemon!!!!!!!!
Scary Face is not a TM or HM in the game. It's a move that Pokemon can learn by level up or by breeding.
All I know of is a Marowak. Just because I just caught it and it had scary face.