pikachu
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Pikachu can.
you have to teach it to them
In Pokemon Platinum, Flash is a TM.
how do you use flash? just go to pokemon and go to the pokemon that knows flash. press A and it will say in blue text "Flash" select that and it will use Flash. it's very useful in dark caves.
In Pokemon diamond many Pokemon can learn flash for eg. Electric Pokemon such as Pachurisu Pichu and Luxray all (eveloutions) and yeah just experiment and see what can learn flash!