Charmander is one of the three starter Pokemon, along with Bulbasaur and Squirtle in these games: Blue, Red, FireRedand LeafGreen.
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You cannot get Mewtwo as a starter Pokemon. The only starter Pokemon available are Charmander, Squirtle, and Bulbasaur. There is no other way to get another starter Pokemon. Mewtwo can only be obtained at the end of the game.
Charmander
Turtwig Charmander Toyodile
You can restart a game and go through the steps until you get to the starter Pokémon. Choose Charmander. i don't think there would be a wild or free charmander in firered
You can not catch a Charmander in Pokemon Firered you must ether choose it as your starter or trade one from Leafgreen