Chansey, Blissey, Clefairy,
and mabee exeggute
maybe hapiny and blissey too?
exeggute can't learn this move softboiled
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Level 13
a healing move
Softboiled can be used outside of battle in all versions and can be used to take away some of Chansey's Health Points in order to heal another Pokemon in your party. Remember that the Pokemon will be rehealed only by the amount of HP taken away from Chansey (Or any other Pokemon using softboiled).
All Pokemon with a water-type can learn it. There are some other Pokemon that can learn it, but mostly water-Pokemon.
I don't know all of the Pokemon that can learn Headbutt, but I know that Cubone can learn it.