Gen 1 - Red and Blue - Charmander, Bulbasaur, Squirtle
Gen 2 - Gold, Silver, Crystal, HeartGold, SoulSilver - Chikorita, Cyndaquil, Totodile
Gen 3 - Ruby, Emerald, Sapphire - Treecko, Mudkip, Torchic
Gen 4 - Diamond, Pearl, Platinum - Chimchar, Turtwig, Piplup
Gen 5 - Black and White - Tepig, Oshawott, Snivy
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no, blaziken is a third generation Pokemon (region: hoenn) and the third form of the starter torchic in rby/spr/emld
You can't catch a starter Pokemon. But to get all of the starters you can trade the Pokemon to another game and restart the game you were playing and get a different starter.
No, simply save your game right before you choose which starter pokemon you want. But be warned you can spend several thousand restarts searching for a shiny starter..
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Piplup is a starter Pokemon in Pokemon Pearl. you can get him early in the game as your starter Pokemon.