Episode 1. He saw Ho-oh
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Yes, Ash did in fact see Ho-Oh in Episode 1 of Pokémon.
Yes it flew over leaving behind a trail of a rainbow
"Wherefore art thou Pokemon" Ash says, "Gee Misty, do you really think a kiss can change someone like that?" Misty says, "We'll have to see"
Because ho-oh only comes to worthy trainers so ho-oh was showing that ash was going to be a great Pokemon trainer.
suicune is top legendary dog just play Pokemon crystal and you'll see.